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Partial aerial oxidation of nonpolar alcohols over Teflon-modified noble metal catalysts in supercritical carbon dioxide

Abstract:

We have reported earlier that modification of commercial graphite Pt-supported catalysts with Teflon fluorinated polymeric coating of a very strong hydrophobic nature can significantly improve catalytic activity for aerial oxidation of water-insoluble alcohols such as anthracene methanol in supercritical carbon dioxide (scCO ). Thus, this paper presents some further characterization of these new catalyst materials and the working fluid phase during the catalysis. Using the same Teflon-modifie...

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Publisher copy:
10.1016/j.jcat.2004.06.008

Authors


Steele, AM More by this author
Journal:
Journal of Catalysis
Volume:
226
Issue:
2
Pages:
435-442
Publication date:
2004-09-10
DOI:
ISSN:
0021-9517
URN:
uuid:5fbfc5a2-3a63-4440-b2da-4826b079e4fc
Source identifiers:
180295
Local pid:
pubs:180295

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