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Synthesis and reactivity of a range of 2-ferrocenyl-3-pivaloyl-1,3-oxazolidin-5-ones

Abstract:
A range of novel 2-ferrocenyl-3-pivaloyl-1,3-oxazolidin-5-ones has been synthesised, both with and without 2-substitution on the ferrocenyl moiety in an effort to develop an asymmetric glycine equivalent. While C-4 alkylation of the parent complex 2-ferrocenyl-3-pivaloyl-1,3-oxazolidin-5-one was successful, the presence of a 2-substituent on the ferrocene ring has been found to prevent C-4 enolisation and hence alkylation.
Publication status:
Published

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Publisher copy:
10.1016/S0022-328X(97)00652-9

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author


Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY More from this journal
Volume:
553
Issue:
1-2
Pages:
463-468
Publication date:
1998-02-25
DOI:
ISSN:
0022-328X


Language:
English
Keywords:
Pubs id:
pubs:110633
UUID:
uuid:5f425467-811a-4b67-a610-5bdbf18026b4
Local pid:
pubs:110633
Source identifiers:
110633
Deposit date:
2012-12-19

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