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Synthesis and evaluation of 4,4 ',6,6 '-tetrasubstituted binaphtholphosphate dirhodium(II) complexes as catalysts in enantioselective carbonyl ylide formation-cycloaddition reactions

Abstract:
The synthesis of tetrakis[4,4′,6,6′-tetrasubstituted-1, 1′-bi-2-naphtholphosphate]dirhodium(II) complexes, and their use as catalysts in the enantioselective tandem carbonyl ylide formation- intramolecular 1,3-dipolar cycloaddition of an unsaturated 2-diazo-3,6- diketoester, generating cycloadduct in up to 86% ee, is described. © 2003 Elsevier Ltd. All rights reserved.
Publication status:
Published

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Publisher copy:
10.1016/j.tetasy.2003.09.029

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author


Journal:
TETRAHEDRON-ASYMMETRY More from this journal
Volume:
14
Issue:
24
Pages:
3841-3849
Publication date:
2003-12-12
DOI:
ISSN:
0957-4166


Language:
English
Pubs id:
pubs:38871
UUID:
uuid:5d8d0db9-28e7-4f6d-9aef-5cc53c0d6a46
Local pid:
pubs:38871
Source identifiers:
38871
Deposit date:
2012-12-19

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