- Abstract:
-
A new macrocyclic amide-substituted cobaltocenium receptor, 1,1′-[(ethylenedioxy)bis(ethyleneaminocarbonyl)]cobaltocenium hexafluorophosphate 2 has been prepared and its single-crystal X-ray structure determined. Proton NMR anion co-ordination studies revealed that 2 and other new acyclic cobaltocenium derivatives complex chloride and bromide anions with 1:1 stoichiometry. Comparative stability constant evaluations imply that the macrocyclic receptor 2 forms halide complexes of greatest therm...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/dt9950003447
-
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- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
- Issue:
- 21
- Pages:
- 3447-3453
- Publication date:
- 1995-11-07
- DOI:
- EISSN:
-
1364-5447
- ISSN:
-
0300-9246
- URN:
-
uuid:5cf762db-3663-480c-b269-36c19180c408
- Source identifiers:
-
45042
- Local pid:
- pubs:45042
- Language:
- English
- Copyright date:
- 1995
Journal article
SYNTHESIS, STRUCTURE AND ANION COORDINATION CHEMISTRY OF A NOVEL MACROCYCLIC COBALTOCENIUM RECEPTOR
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