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SYNTHESIS, STRUCTURE AND ANION COORDINATION CHEMISTRY OF A NOVEL MACROCYCLIC COBALTOCENIUM RECEPTOR

Abstract:

A new macrocyclic amide-substituted cobaltocenium receptor, 1,1′-[(ethylenedioxy)bis(ethyleneaminocarbonyl)]cobaltocenium hexafluorophosphate 2 has been prepared and its single-crystal X-ray structure determined. Proton NMR anion co-ordination studies revealed that 2 and other new acyclic cobaltocenium derivatives complex chloride and bromide anions with 1:1 stoichiometry. Comparative stability constant evaluations imply that the macrocyclic receptor 2 forms halide complexes of greatest therm...

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Publication status:
Published

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Publisher copy:
10.1039/dt9950003447

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
21
Pages:
3447-3453
Publication date:
1995-11-07
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:5cf762db-3663-480c-b269-36c19180c408
Source identifiers:
45042
Local pid:
pubs:45042
Language:
English

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