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Investigation of the GeO2-1,6-diaminohexane-water-pyridine-HF phase diagram leading to the discovery of two novel layered germanates with extra-large rings.

Abstract:

The systematic exploration of the phase diagram of the GeO(2)-1,6-diaminohexane-water-pyridine-HF system has allowed the identification of specific roles of the HF, H(2)O contents, and HF/H(2)O ratio in the formation of Ge(7)X(19) (Ge(7)), Ge(9)X(25-26) (Ge(9)), and Ge(10)X(28) (Ge(10)) clusters (X = O, OH, F). This work has led to the discovery of two novel structures with extra-large 18-membered rings accommodating 1,6-diaminohexane (DAH): SU-63, |1.5H(2)DAH|[Ge(7)O(14)X(3)]·2H(2)O, a layer...

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Publication status:
Published

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Publisher copy:
10.1021/ic1017505

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
Inorganic chemistry
Volume:
50
Issue:
1
Pages:
201-207
Publication date:
2011-01-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:5c77f1e3-1e5d-4754-89b9-23b39e63e7b2
Source identifiers:
321977
Local pid:
pubs:321977
Language:
English

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