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Investigations of N@C60 and N@C70 stability under high pressure and high temperature conditions

Abstract:

Endohedral fullerenes encapsulating single nitrogen atoms (N@C60 and N@C70) are spin active, due to the presence of unpaired nitrogen electron spins. High reactivity of nitrogen leads to a poor stability of these molecules at elevated temperatures, drastically restricting possibilities of their chemical treatment. In this study, N@C60 and N@C70 in toluene solutions were subjected to high pressure (HP) up to 0.8 GPa and annealed for 1, 2, 10 or 24 h, at either room or elevated temperatures. In...

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Publisher copy:
10.1002/pssb.200982270

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Institution:
University of Oxford
Department:
Oxford, MPLS, Materials
Role:
Author
Journal:
Physica Status Solidi (B) Basic Research
Volume:
246
Issue:
11-12
Pages:
2767-2770
Publication date:
2009-12-05
DOI:
EISSN:
1521-3951
ISSN:
0370-1972
URN:
uuid:5c724ac7-ebc7-4cc0-be4c-7f338bdc7d66
Source identifiers:
178957
Local pid:
pubs:178957
Language:
English

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