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Computation of currents at microelectrodes using hp-DGFEM

Abstract:
We describe how a discontinuous Galerkin finite element method with interior penalty can be used to compute the current flowing at a microdisc electrode for the steady-state E and EC′ reaction mechanisms and at a channel microband electrode for the steady-state E, ECE, EC2E, DISP1 and DISP2 reaction mechanisms. We then state an a posteriori error bound for the computed current and use this as the basis of an hp-adaptive discontinuous Galerkin finite element algorithm to deliver the current to within a prescribed error tolerance. For all problems we demonstrate excellent agreement with previous results using comparatively coarse meshes. © 2005 Elsevier B.V. All rights reserved.
Publication status:
Published

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Publisher copy:
10.1016/j.jelechem.2005.09.028

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Mathematical Institute
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Mathematical Institute
Role:
Author


Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY More from this journal
Volume:
587
Issue:
1
Pages:
1-17
Publication date:
2006-02-01
DOI:
ISSN:
0022-0728


Language:
English
Keywords:
Pubs id:
pubs:131818
UUID:
uuid:5be6dcc8-d953-419b-a556-dfefc73c77e2
Local pid:
pubs:131818
Source identifiers:
131818
Deposit date:
2012-12-19

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