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Electrochemical Kinetics of Ag/Ag+ and TMPD|TMPD+. in the Room-Temperature Ionic Liquid [C4mpyrr][NTf2]; toward Optimizing Reference Electrodes for Voltammetry in RTILs

Abstract:

The voltammetry and kinetics of the Ag|Ag+ system (commonly used as a reference electrode material in both protic/aprotic and RTIL solvents) was studied in the room-temperature ionic liquid N-buty1-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, [C4mpyrr] [NTf2] on a 10 μm diameter Pt electrode. For the three silver salts investigated (AgOTf, AgNTf2, and AgNO3, where OTf- = trifluoromethanesulfonate, NTf2- = bis(trifluoromethylsulfonyl)imide, and NO 3- = nitrate), the voltammetry gav...

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Publication status:
Published
Peer review status:
Peer Reviewed

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Publisher copy:
10.1021/jp0737754

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
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Publisher:
ACS Publications Publisher's website
Journal:
The Journal of Physical Chemistry C Journal website
Volume:
111
Issue:
37
Pages:
13957-13966
Publication date:
2007-09-20
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
URN:
uuid:5ad0e76f-a85a-4d50-8ce1-699321abe6fe
Source identifiers:
168601
Local pid:
pubs:168601
Language:
English

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