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LACK OF GLYCOSIDASE INHIBITION BY, AND ISOLATION FROM XANTHOCERCIS-ZAMBESIACA (LEGUMINOSAE) OF, 4-0-(BETA-D-GLUCOPYRANOSYL)-FAGOMINE [1,2,5-TRIDEOXY-4-0-(BETA-D-GLUCOPYRANOSYL)-1,5-IMINO-D-ARABINO-HEXITOL], A NOVEL GLUCOSIDE OF A POLYHYDROXYLATED PIPERIDINE ALKALOID

Abstract:
A COSY spectrum has been used to determine the position of inter-residue linkage in 4-O-(β-D-glucopyranosyl) fagomine (1) an example of a new class of glycosides of polyhydroxylated piperidine alkaloids isolated from seed of the legume Xanthocercis zambesiaca. (Bak.) Dunn. Unlike a number of polyhydroxylated piperidines, neither the glucoside (1) nor free fagomine [1,2,5-trideoxy-1,5-imino-D-arabinohexitol] (3) showed any inhibitory activity towards glycosidase enzymes from a variety of sources. © 1985.
Publication status:
Published

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Journal:
TETRAHEDRON LETTERS
Volume:
26
Issue:
11
Pages:
1465-1468
Publication date:
1985-01-01
DOI:
ISSN:
0040-4039
URN:
uuid:5acb72d7-e3c1-46bb-bf0e-42c9583d7eaa
Source identifiers:
42387
Local pid:
pubs:42387
Language:
English

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