Journal article

Enzyme-catalysed enantioselective oxidation of alcohols by air exploiting fast electrochemical nicotinamide cycling in electrode nanopores

Abstract:: Enantioselective conversion of alcohols to ketones using air as the oxidant is achieved with high rates and efficiency using an indium tin oxide (ITO) electrode in which an alcohol dehydrogenase and a photosynthetic NADPH recycling enzyme are confined within nanopores. The massive catalytic enhancement arising from nanoconfinement is exploited in an air-driven electrochemical cell, which requires no complicating control features yet allows continuous monitoring of the reaction via the current that flows between anode (ITO: organic chemistry) and cathode (Pt: O2 from air).

Publication status:: Published

Peer review status:: Peer reviewed

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APA Style

Wan, L., Heath, R., Siritanaratkul, B., Megarity, C., Sills, A., Thompson, M., Turner, N., & Armstrong, F. (2019). Enzyme-catalysed enantioselective oxidation of alcohols by air exploiting fast electrochemical nicotinamide cycling in electrode nanopores. Green Chemistry, 21(18), 4958–4963.

MLA Style

Wan, L., et al. “Enzyme-Catalysed Enantioselective Oxidation of Alcohols by Air Exploiting Fast Electrochemical Nicotinamide Cycling in Electrode Nanopores.” Green Chemistry, vol. 21, no. 18, Royal Society of Chemistry, 2019, pp. 4958–63.

Chicago Style

Wan, L, R Heath, B Siritanaratkul, C Megarity, A Sills, M Thompson, N Turner, and F Armstrong. 2019. “Enzyme-Catalysed Enantioselective Oxidation of Alcohols by Air Exploiting Fast Electrochemical Nicotinamide Cycling in Electrode Nanopores.” Green Chemistry 21 (18): 4958–63.
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Files:: c9gc01534e.pdf

(Preview, Version of record, pdf, 1.1MB, Terms of use)

Publisher copy:: 10.1039/C9GC01534E

Authors

+ Wan, L More by this author

Institution:: University of Oxford
Division:: MPLS Division
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Heath, R More by this author

Role:: Author

+ Siritanaratkul, B More by this author

Institution:: University of Oxford
Division:: MPLS Division
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Megarity, C More by this author

Institution:: University of Oxford
Division:: MPLS Division
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Sills, A More by this author

Institution:: University of Oxford
Division:: MPLS Division
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

More authors...

+ Biotechnology & Biological Sciences Research Council More from this funder

Grant:: BB/P023797/1

Publisher:: Royal Society of Chemistry
Journal:: Green Chemistry More from this journal
Volume:: 21
Issue:: 18
Pages:: 4958-4963
Publication date:: 2019-08-30
Acceptance date:: 2019-07-15
DOI:: 10.1039/C9GC01534E
ISSN:: 1463-9270

Pubs id:: pubs:1035903
UUID:: uuid:5a5de69d-6a2a-46c1-99ef-626be46450d2
Local pid:: pubs:1035903
Source identifiers:: 1035903
Deposit date:: 2019-07-29

Terms of use

Copyright date:: 2019
Notes:: This is an open access article distributed under the terms of the Creative Commons Attribution Licence

Licence:: CC Attribution (CC BY)

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