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Semi-circular sweep voltammetry. Bio-analytical applications

Abstract:
A novel voltammetric method applying a semi-circular potential sweep is applied to the simultaneous electroanalytical determination of solutions containing two components with similar oxidation potentials which precludes their resolution using conventional voltammetric methods including linear sweep, square wave and pulse voltammetries. Three such biologically important mixtures, ascorbic acid/acetaminophen, glucose/ethanol and hydroquinone/catechol were studied, analytical methods developed and the method of semi-circular sweep voltammetry shown to give notable advantages over the other conventional analytical voltammetries in terms of signal resolution and the sensitivity of the detection. Favourable accuracy was obtained using electrodes with either simple or no modification in the established linear detection ranges.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.bios.2021.113083

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Oxford college:
Wadham College
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Publisher:
Elsevier
Journal:
Biosensors and Bioelectronics More from this journal
Volume:
179
Article number:
113083
Publication date:
2021-02-10
Acceptance date:
2021-02-03
DOI:
EISSN:
1873-4235
ISSN:
0956-5663


Language:
English
Keywords:
Pubs id:
1161896
Local pid:
pubs:1161896
Deposit date:
2021-02-23
ARK identifier:

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