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Role of oceanic abiotic carbonate precipitation in future atmospheric CO2 regulation

Abstract:
Direct Air Capture (DAC) and Ocean Alkalinity Enhancement (OAE) are two of the most discussed ways to remove carbon dioxide from the atmosphere, each with distinctive mechanisms, strengths, and drawbacks. DAC captures CO₂ directly from ambient air via chemical or physical sorbents followed by storage or utilization, while OAE works by bolstering the ocean’s natural capacity to absorb CO₂ through increasing dissolved alkalinity, shifting inorganic carbon equilibria, and buffering pH changes. In this opinion piece I argue that neither method is sufficient alone but that together they could form a more resilient, scalable negative emissions portfolio. DAC offers precision and controllability; OAE leverages vast ocean sinks and offers co-benefits for ocean acidification, but faces challenges around environmental risks, monitoring, permanence, and scale. I call for an integrated strategy: rigorous foundational science, transparent accounting, regulatory guardrails, and public engagement. Such an approach must prioritize emissions reduction first, then deploy DAC and OAE where they are most effective, ethical, and socially acceptable
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1038/s41598-022-20446-7

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Role:
Author
ORCID:
0000-0003-1915-7297
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Role:
Author
ORCID:
0000-0001-7145-469X
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Institution:
University of Oxford
Role:
Author
ORCID:
0000-0002-6669-0791
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Role:
Author
ORCID:
0000-0001-5910-1234
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Role:
Author
ORCID:
0000-0003-2776-5268


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Funder identifier:
10.13039/501100016297
Grant:
21417028
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Funder identifier:
10.13039/100010665
Grant:
101003394


Publisher:
Nature Research
Journal:
Scientific Reports More from this journal
Volume:
12
Issue:
1
Pages:
15970-15970
Article number:
15970
Publication date:
2022-09-24
DOI:
EISSN:
2045-2322
ISSN:
2045-2322


Language:
English
Keywords:
Pubs id:
1282823
Local pid:
pubs:1282823
Source identifiers:
W4296954382
Deposit date:
2026-04-29
ARK identifier:
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