- The addition of Grignard reagents or organolithium reagents to the SO2-surrogate DABSO generates a diverse set of metal sulfinates, suitable for direct conversion to sulfone products. The metal sulfinates can be trapped in situ with a wide range of C-electrophiles, including alkyl, allyl, and benzyl halides, epoxides, and (hetero)aryliodoniums.
- Publication status:
- Peer review status:
- Peer reviewed
- Publisher's version
- Copyright holder:
- American Chemical Society
- Copyright date:
- Copyright © 2013 American Chemical Society. Under Creative Commons Attribution 4.0 International license.
DABSO-based, three-component, one-pot sulfone synthesis.
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