- Abstract:
- The addition of Grignard reagents or organolithium reagents to the SO2-surrogate DABSO generates a diverse set of metal sulfinates, suitable for direct conversion to sulfone products. The metal sulfinates can be trapped in situ with a wide range of C-electrophiles, including alkyl, allyl, and benzyl halides, epoxides, and (hetero)aryliodoniums.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's version
- Files:
-
-
(pdf, 289.8kb)
-
- Publisher copy:
- 10.1021/ol403122a
-
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- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Organic letters Journal website
- Volume:
- 16
- Issue:
- 1
- Pages:
- 150-153
- Publication date:
- 2013-12-05
- DOI:
- EISSN:
-
1523-7052
- ISSN:
-
1523-7060
- URN:
-
uuid:58324890-5cff-4d41-bc8c-ac98e7afb76c
- Source identifiers:
-
441788
- Local pid:
- pubs:441788
- Language:
- English
- Keywords:
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2013
- Notes:
- Copyright © 2013 American Chemical Society. Under Creative Commons Attribution 4.0 International license.
Journal article
DABSO-based, three-component, one-pot sulfone synthesis.
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Engineering and Physical Sciences Research Council
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