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DABSO-based, three-component, one-pot sulfone synthesis.

Abstract:
The addition of Grignard reagents or organolithium reagents to the SO2-surrogate DABSO generates a diverse set of metal sulfinates, suitable for direct conversion to sulfone products. The metal sulfinates can be trapped in situ with a wide range of C-electrophiles, including alkyl, allyl, and benzyl halides, epoxides, and (hetero)aryliodoniums.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1021/ol403122a

Authors


Deeming, AS More by this author
Russell, CJ More by this author
Hennessy, AJ More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Engineering and Physical Sciences Research Council More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Organic letters Journal website
Volume:
16
Issue:
1
Pages:
150-153
Publication date:
2013-12-05
DOI:
EISSN:
1523-7052
ISSN:
1523-7060
URN:
uuid:58324890-5cff-4d41-bc8c-ac98e7afb76c
Source identifiers:
441788
Local pid:
pubs:441788

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