Journal article

Anion sensing by solution- and surface-assembled osmium(II) bipyridyl rotaxanes

Abstract:: We report the preparation of [2]rotaxanes containing an electrochemically and optically active osmium(II) bipyridyl macrocyclic component mechanically bonded with cationic pyridinium axles. Such interlocked host systems are demonstrated to recognise and sense anionic guest species as shown by 1HNMR, luminescence and electrochemical studies. The rotaxanes can be surface assembled on to gold electrodes through anion templation under click copper(I)-catalysed Huisgen cycloaddition conditions to form rotaxane molecular films, which, after template removal, respond electrochemically and selectively to chloride. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.

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APA Style

Lehr, J., Lang, T., Blackburn, O., Barendt, T., Faulkner, S., Davis, J., & Beer, P. (2013). Anion sensing by solution- and surface-assembled osmium(II) bipyridyl rotaxanes. Chemistry - A European Journal, 19(47), 15898–15906.

MLA Style

Lehr, J., et al. “Anion Sensing by Solution- and Surface-Assembled Osmium(II) Bipyridyl Rotaxanes.” Chemistry - A European Journal, vol. 19, no. 47, Wiley, 2013, pp. 15898–906.

Chicago Style

Lehr, J, T Lang, O Blackburn, T Barendt, S Faulkner, J Davis, and P Beer. 2013. “Anion Sensing by Solution- and Surface-Assembled Osmium(II) Bipyridyl Rotaxanes.” Chemistry - A European Journal 19 (47): 15898–906.
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Publisher copy:: 10.1002/chem.201302886

Authors

+ Lehr, J More by this author

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+ Lang, T More by this author

Role:: Author

+ Blackburn, O More by this author

Role:: Author

+ Barendt, T More by this author

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+ Faulkner, S More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

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Publisher:: Wiley
Journal:: Chemistry - A European Journal More from this journal
Volume:: 19
Issue:: 47
Pages:: 15898-15906
Publication date:: 2013-11-18
DOI:: 10.1002/chem.201302886
EISSN:: 1521-3765
ISSN:: 0947-6539

Language:: English
Keywords:: anion sensing

rotaxanes

self-assembly

surface immobilization

osmium
Pubs id:: pubs:459247
UUID:: uuid:57d3cffd-1f33-4834-a84d-38fb320d9cdd
Local pid:: pubs:459247
Source identifiers:: 459247
Deposit date:: 2014-05-12

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Copyright date:: 2013

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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