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In-situ conductivity and Seebeck measurements of highly efficient n-dopants in fullerene C60

Abstract:
We present two organic dimetal complexes Cr2(hpp)4 and W2(hpp)4 as n-dopants investigated in the model system of fullerene C60 for the application in organic electronic devices. Conductivity and Seebeck measurements on doped layers are carried out in vacuum at different doping concentrations and various substrate temperatures to compare the two dopants. Very high conductivities of up to 4 S/cm are achieved for both organic dopants. The thermal activation energy of the conductivity as well as the measured Seebeck coefficient are found to decrease with increasing doping concentration, indicating a shift of the Fermi level towards the electron transport level of the n-doped C60. © 2012 American Institute of Physics.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1063/1.3689778

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Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author


Publisher:
American Institute of Physics
Journal:
Applied Physics Letters More from this journal
Volume:
100
Issue:
9
Article number:
093304
Publication date:
2012-02-27
DOI:
ISSN:
0003-6951


Language:
English
Pubs id:
pubs:405353
UUID:
uuid:57a0b86d-5ca3-4d76-bf3c-4e6bb39cbb51
Local pid:
pubs:405353
Source identifiers:
405353
Deposit date:
2013-09-26

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