Prediction of Frozen-In Birefringence in Oriented Glassy Polymers Using a Molecularly Aware Constitutive Model Allowing for Finite Molecular Extensibility

Journal article

A study has been made of birefringence in oriented glassy polystyrene. The aim was to develop a methodology for the prediction of birefringence in glassy polymers with frozen-in molecular orientation. The predictive approach employed was to use a recently proposed constitutive model, consisting of a coupling between the Likhtman-Graham Rolie-Poly model for polymer melt rheology and a previously established model for polymer glasses. The methodology was validated with an experimental study of oriented glassy polystyrenes with known melt-stretching histories. It was found that, for orientation processes sufficiently far above Tg (i.e., not including subentanglement stretch), birefringence could be predicted accurately in monodisperse materials. © 2011 American Chemical Society.

Authors: De Focatiis, D; Buckley, C

• Publication status: Published
• Journal: MACROMOLECULES
• Volume: 44
• Issue: 8
• Pages: 3085-3095
• Publication date: 2011-04-26
• DOI: 10.1021/ma102906z
• EISSN: 1520-5835
• ISSN: 0024-9297
• Language: English