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Dithiocarbamate ligand stabilised gold nanoparticles

Abstract:
Dithiocarbamates are used as adsorbates for the preparation of gold nanoparticles. A range of mono- and tetrakis-functionalised dithiocarbamate ligands containing alkyl, benzyl and resorcinarene cavitand substituents are synthesised. Nanoparticles are prepared by a two-phase synthesis and are characterised by 1H NMR spectroscopy, UV-Visible spectroscopy, transmission electron microscopy (TEM), energy dispersive X-ray analysis (EDX) and elemental analysis. The colloids are found to be stable over a number of months storage in air. The synthetic versatility of the dithiocarbamate ligand is further demonstrated by the synthesis of ruthenium(ii) bipyridyl dithiocarbamate capped gold nanoparticles. © The Royal Society of Chemistry 2006.
Publication status:
Published

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Publisher copy:
10.1039/b509173j

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
JOURNAL OF MATERIALS CHEMISTRY More from this journal
Volume:
16
Issue:
2
Pages:
209-215
Publication date:
2006-01-01
DOI:
EISSN:
1364-5501
ISSN:
0959-9428


Language:
English
Pubs id:
pubs:39733
UUID:
uuid:56f68afc-7e01-4489-9d5c-f2e7b5786476
Local pid:
pubs:39733
Source identifiers:
39733
Deposit date:
2012-12-19

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