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On the adiabaticity of electrode processes: Effect of the supporting electrolyte cation on the kinetics of electroreduction of 3-nitrophenolate

Abstract:

The comparative analysis of voltammetric responses at different temperatures through the asymmetric Marcus-Hush theory provides physical insight into the changes upon the electron transfer mechanism and the electronic interaction between the electrode and the electroactive species. Herein this approach is applied to the assessment of the influence of the nature of the supporting electrolyte on the kinetics of electrode processes. In particular, the electroreduction of the 3-nitrophenolate ani...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
694
Pages:
30-36
Publication date:
2013-04-01
DOI:
ISSN:
1572-6657
Source identifiers:
394083
Language:
English
Keywords:
UUID:
uuid:569d03e1-e5df-44f8-a99e-bec0dc372ba8
Local pid:
pubs:394083
Deposit date:
2013-11-16

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