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Thesis

Asymmetric synthesis via iron acyl complexes

Abstract:

This thesis describes the applications to asymmetric synthesis of the highly diastereoselective carbon-carbon bond forming reactions of α,β-unsaturated acyl ligands bound to the chiral iron auxiliary [(η5-C5H5)Fe(CO)(PPh3)].

Chapter 1 briefly reviews the use of chiral auxiliaries in asymmetric synthesis.

Chapter 2 discusses the conformation of [(η5-C5H5)Fe(CO)(PPh3)COCH3] with re...

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Institution:
University of Oxford
Department:
Mathematical and Physical Sciences Division

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Role:
Supervisor
Role:
Supervisor
Publication date:
1986
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Barcode:
603839428
URN:
uuid:55cfc478-5868-474f-9d2b-532218ec6fd6
Local pid:
td:603839428

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