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Square wave voltammetry at disc microelectrodes for characterization of two electron redox processes.

Abstract:

Analytical explicit solutions are presented for the use of square wave voltammetry (SWV) at disc microelectrodes to study two-electron reversible redox processes. This combines the advantages of SWV (minimization of capacitative effects, peak-shaped response and quick experiments) with those of microelectrodes (reduction of capacitative and ohmic drop effects, enhanced mass transport and measurements of small volumes). Further, the analytical expressions are very easy to implement in comparis...

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Publication status:
Published

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Publisher copy:
10.1039/c2cp40265c

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
14
Issue:
23
Pages:
8319-8327
Publication date:
2012-06-01
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Source identifiers:
332760
Language:
English
Keywords:
UUID:
uuid:55b3feef-a2b9-4014-a4f8-9a7d991bfe9c
Local pid:
pubs:332760
Deposit date:
2012-12-19

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