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Palladium-catalyzed coupling of ammonia and hydroxide with aryl halides: the direct synthesis of primary anilines and phenols.

Abstract:
(Chemical Equation Presented) Back to basics: Ligand design has allowed two longstanding limitations of Pd-catalyzed C-N and C-O coupling reactions to be overcome. The use of specific sterically demanding electron-rich phosphine ligands makes it possible for ammonia and potassium hydroxide to act as coupling partners in palladium-catalyzed coupling with aryl halides. © 2007 Wiley-VCH Verlag GmbH and. Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200605071

Authors


Willis, MC More by this author
Journal:
Angewandte Chemie (International ed. in English)
Volume:
46
Issue:
19
Pages:
3402-3404
Publication date:
2007
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:55216a6e-6afe-400f-9f3f-5e79ec689c62
Source identifiers:
52470
Local pid:
pubs:52470

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