Journal article

Trifluoromethylation of allylsilanes under photoredox catalysis.

Abstract:: A new catalytic method to access allylic secondary CF3 products is described. These reactions use the visible light excited Ru(bpy)3Cl2·6H2O catalyst and the Togni or Umemoto reagent as the CF3 source. The photoredox catalytic manifold delivers enantioenriched allylic trifluoromethylated products not accessible under Cu(I) catalysis.

Publication status:: Published

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APA Style

Mizuta, S., Engle, K., Verhoog, S., Galicia-López, O., O'Duill, M., Médebielle, M., Wheelhouse, K., Rassias, G., Thompson, A., & Gouverneur, V. (2013). Trifluoromethylation of allylsilanes under photoredox catalysis. Organic Letters, 15(6), 1250–1253.

MLA Style

Mizuta, S., et al. “Trifluoromethylation of Allylsilanes under Photoredox Catalysis.” Organic Letters, vol. 15, no. 6, 2013, pp. 1250–53.

Chicago Style

Mizuta, S, K Engle, S Verhoog, O Galicia-López, M O'Duill, M Médebielle, K Wheelhouse, G Rassias, A Thompson, and V Gouverneur. 2013. “Trifluoromethylation of Allylsilanes under Photoredox Catalysis.” Organic Letters 15 (6): 1250–53.
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Publisher copy:: 10.1021/ol400184t

Authors

+ Mizuta, S More by this author

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+ Engle, K More by this author

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+ Verhoog, S More by this author

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+ Galicia-López, O More by this author

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+ O'Duill, M More by this author

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Journal:: Organic letters More from this journal
Volume:: 15
Issue:: 6
Pages:: 1250-1253
Publication date:: 2013-03-01
DOI:: 10.1021/ol400184t
EISSN:: 1523-7052
ISSN:: 1523-7060

Language:: English
Keywords:: Catalysis

Light

Copper

Hydrocarbons, Fluorinated

Molecular Structure

Photochemical Processes

Stereoisomerism

Combinatorial Chemistry Techniques

Silanes
Pubs id:: pubs:387757
UUID:: uuid:54c1bee7-6fc9-4801-8c24-72d2ba6c7442
Local pid:: pubs:387757
Source identifiers:: 387757
Deposit date:: 2013-11-16

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Copyright date:: 2013

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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