Photoelectrochemical Water‐Splitting Using CuO‐Based Electrodes for Hydrogen Production: A Review

Siavash Moakhar, R; Hosseini-Hosseinabad, SM; Masudy-Panah, S; Seza, A; Jalali, M; Fallah-Arani, H; Dabir, F; Gholipour, S; Abdi, Y; Bagheri-Hariri, M; Riahi-Noori, N; Lim, Y-F; Hagfeldt, A; Saliba, M

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Journal article

Photoelectrochemical Water‐Splitting Using CuO‐Based Electrodes for Hydrogen Production: A Review

Abstract:: [EN] Two novel three-dimensional metal-organic frameworks(MOFs)based on the photoactive pyrene tetraphosphonate ligand and copper(denoted as IEF-8 and IEF-9) have been hydrothermally synthesizedand fully characterized (XRD, FTIR, TGA, SEM, XPS, etc.). Their crystalstructures were unveiled by single-crystal X-ray diffraction. Remarkably,these materials exhibit coordinatively unsaturated copper (II) sites,free -PO3H2 and -PO3H acidic groups, and good thermal and chemical stability. Further,their optoelectronic characterization evidenced a photoresponse suitablefor photocatalysis. In this sense, the photocatalytic activity ofpyrene phosphonate MOFs was evaluated for the first time for the challenginghydrogen evolution reaction. In particular, IEF-8 exhibited a catalyticefficiency higher than that of the benchmarked Ti carboxylate photocatalystMIL-125-(Ti)-NH2, producing 1800 mu mol center dot g(-1) after 22 h under UV-vis irradiation in theabsence of any co-catalyst. Furthermore, this material presented goodreusability (at least up to 4 cycles), preserving its activity andstructural integrity.The authors acknowledge the Maria de Maeztu IMDEA Energy Institute, the M-ERA-NET C-MOF-cell project, the Retos Investigacion MOFSEIDON project (PID2019-104228RB-I00 funded by MCIN/AEI/10.13039/501100011033 and by the European Union, MICIU-AEI/FEDER, UE), and the H2-MOF project (TED2021-132092B-C21 funded by MCIN/AEI/10.13039/501100011033 and by the European Union NextGenerationEU/PRTR). They thank "Comunidad de Madrid" and European Regional Development Fund-FEDER 2014-2020-OE REACT-UE 1for their financial support to the VIRMOF-CM project associated to R & D projects in response to COVID-19. S.N. thanks the support of grant PID2021-123856OBI00 funded by MCIN/AEI/10.13039/501100011033 and by ERDF A way of making Europe.Salcedo-Abraira, P.; Serrano Nieto, R.; Biglione, C.; Cabrero-Antonino, M.; Vilela, SM.; Babaryk, AA.; Tilve-Martínez, D.... (2023). Two Cu-Based Phosphonate Metal-Organic Frameworks as Efficient Water-Splitting Photocatalysts. Chemistry of Materials. 35(11):4211-4219. https://doi.org/10.1021/acs.chemmater.3c0005442114219351

Publication status:: Published

Peer review status:: Peer reviewed

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APA Style

Siavash Moakhar, R., Hosseini-Hosseinabad, S. M., Masudy-Panah, S., Seza, A., Jalali, M., Fallah-Arani, H., Dabir, F., Gholipour, S., Abdi, Y., Bagheri-Hariri, M., Riahi-Noori, N., Lim, Y.-F., Hagfeldt, A., & Saliba, M. (2021). Photoelectrochemical Water‐Splitting Using CuO‐Based Electrodes for Hydrogen Production: A Review. Advanced Materials, 33(33), e2007285–e2007285.

MLA Style

Siavash Moakhar, R, et al. “Photoelectrochemical Water‐Splitting Using CuO‐Based Electrodes for Hydrogen Production: A Review.” Advanced Materials, vol. 33, no. 33, 2021, pp. e2007285–e2007285.

Chicago Style

Siavash Moakhar, R, SM Hosseini-Hosseinabad, S Masudy-Panah, et al. 2021. “Photoelectrochemical Water‐Splitting Using CuO‐Based Electrodes for Hydrogen Production: A Review.” Advanced Materials 33 (33): e2007285–e2007285.
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