Crystal Structure of Tetrabutylammonium Chloride Complex with <i>Rac</i>-1,1′-bi-2-naphthol: The Inclusion of Surfactant Molecules by Hydrogen Bonded Binaphthol Molecules

Journal article

The tetrabutylammonium chloride complex with rac-1,1′-bi-2-naphthol crystallizes in monoclinic space group P21/n, with unit-cell parameters of; a = 10.4941(1)Å, b = 26.3302(3)Å, c = 11.5290(1)Å, α = 90°, β = 100.0154(5)°, γ = 90 °, V = 3137.05(5)Å3, and Z = 4. The packing mode, hydrogen bonding network, and crystal data suggest that the crystal structure is isomorphous with the reported structure of a tetrabutylammonium bromide complex with rac-1,1′-bi-2-naphthol.2.

Authors: MARFO-OWUSU, E; THOMPSON, AL

• Publication status: Published
• Peer review status: Peer reviewed
• Publisher: Japan Society for Analytical Chemistry
• Journal: X-ray Structure Analysis Online
• Volume: 37
• Issue: 0
• Pages: 27-28
• Publication date: 2021-06-09
• DOI: 10.2116/xraystruct.37.27
• ISSN: 1883-3578
• Language: English
• Keywords: Organic chemistry; Chemistry; Crystal (programming language); Crystal structure; Materials science; Bromide; Monoclinic crystal system; Crystallography; Inorganic chemistry; Hydrogen bond; Pulmonary surfactant; Chloride; Molecule