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Triheterometallic lanthanide complexes made from kinetically inert lanthanide building blocks

Abstract:

Three molecular structures, each containing three different lanthanide(III) centres, were made by coupling three kinetically inert lanthanide(III) complexes in an Ugi reaction. These 2 kDa molecules were purified by dialysis, and characterised using NMR and luminescence. The photophysical properties of these heterotrimetallic complexes were investigated and are discussed by comparison with simpler, but related, heterobimetallic compounds. It was found that an amino-naphthalene unit inhibits s...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1002/ejic.201700027

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Institution:
University of Oxford
Department:
Keble College
Role:
Author
University of Oxford More from this funder
University of Durham More from this funder
Danish Council for Independent Research More from this funder
Carlsberg Foundation More from this funder
Christ Church College, Oxford More from this funder
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Publisher:
Wiley-VCH Verlag Publisher's website
Journal:
European Journal of Inorganic Chemistry Journal website
Volume:
2017
Issue:
15
Pages:
2165–2172
Publication date:
2017-02-02
Acceptance date:
2017-01-31
DOI:
EISSN:
1099-0682
ISSN:
1434-1948
Pubs id:
pubs:675629
URN:
uri:53c03be0-1dbb-4622-8740-989397f52ffb
UUID:
uuid:53c03be0-1dbb-4622-8740-989397f52ffb
Local pid:
pubs:675629
Paper number:
15

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