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Charge-carrier mobilities in metal halide perovskites: Fundamental mechanisms and limits

Abstract:
Perovskite photovoltaic cells have seen a remarkable rise in power conversion efficiencies over a period of only a few years. Much of this performance is underpinned by the favorable chargecarrier mobilities in metal halide perovskites (MHPs), which are remarkably high for materials with such facile and versatile processing routes. This Perspective outlines the mechanisms that set a fundamental upper limit to charge-carrier mobility values in MHPs and reveals how they may be tuned through changes in stoichiometry. In addition, extrinsic effects such as grain size, energetic disorder, and self-doping are discussed for specific MHPs in the context of remedies designed to avoid them.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acsenergylett.7b00276

Authors


More by this author
Institution:
University of Oxford
Oxford college:
Nuffield College
Role:
Author


Publisher:
American Chemical Society
Journal:
ACS Energy Letters More from this journal
Publication date:
2017-05-01
Acceptance date:
2017-05-31
DOI:
ISSN:
2380-8195


Pubs id:
pubs:707880
UUID:
uuid:53604051-e74f-4843-8d33-4f8af3ab49d2
Local pid:
pubs:707880
Source identifiers:
707880
Deposit date:
2017-07-13

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