Journal article icon

Journal article

Imaging photon-initiated reactions: a study of the Cl(2P(3/2))+CH4-->HCl+CH3 reaction.

Abstract:

The hydrogen or deuterium atom abstraction reactions between Cl((2)P(3/2)) and methane, or its deuterated analogues CD(4) and CH(2)D(2), have been studied at mean collision energies around 0.34 eV. The experiments were performed in a coexpansion of molecular chlorine and methane in helium, with the atomic Cl reactants generated by polarized laser photodissociation of Cl(2) at 308 nm. The Cl-atom reactants and the methyl radical products were detected using (2+1) resonantly enhanced multiphoto...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1063/1.2009737

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
The Journal of chemical physics
Volume:
123
Issue:
9
Pages:
94301
Publication date:
2005-09-05
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
URN:
uuid:52cdd7ff-7bf7-4fee-ad2f-b59d6722a697
Source identifiers:
33229
Local pid:
pubs:33229
Language:
English

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP