- Abstract:
-
The hydrogen or deuterium atom abstraction reactions between Cl((2)P(3/2)) and methane, or its deuterated analogues CD(4) and CH(2)D(2), have been studied at mean collision energies around 0.34 eV. The experiments were performed in a coexpansion of molecular chlorine and methane in helium, with the atomic Cl reactants generated by polarized laser photodissociation of Cl(2) at 308 nm. The Cl-atom reactants and the methyl radical products were detected using (2+1) resonantly enhanced multiphoto...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1063/1.2009737
-
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- Journal:
- The Journal of chemical physics
- Volume:
- 123
- Issue:
- 9
- Pages:
- 94301
- Publication date:
- 2005-09-05
- DOI:
- EISSN:
-
1089-7690
- ISSN:
-
0021-9606
- URN:
-
uuid:52cdd7ff-7bf7-4fee-ad2f-b59d6722a697
- Source identifiers:
-
33229
- Local pid:
- pubs:33229
- Language:
- English
- Copyright date:
- 2005
Journal article
Imaging photon-initiated reactions: a study of the Cl(2P(3/2))+CH4-->HCl+CH3 reaction.
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