Element specific atom counting at the atomic scale by combining high angle annular dark field scanning transmission electron microscopy and energy dispersive X-ray spectroscopy

Journal article

A new methodology is presented to count the number of atoms in multimetallic nanocrystals by combining energy dispersive X-ray spectroscopy (EDX) and high angle annular dark field scanning transmission electron microscopy (HAADF STEM). For this purpose, the existence of a linear relationship between the incoherent HAADF STEM and EDX images is exploited. Next to the number of atoms for each element in the atomic columns, the method also allows quantification of the error in the obtained number of atoms, which is of importance given the noisy nature of the acquired EDX signals. Using experimental images of an Au@Ag core-shell nanorod, it is demonstrated that 3D structural information can be extracted at the atomic scale. Furthermore, simulated data of an Au@Pt core-shell nanorod show the prospect to characterize heterogeneous nanostructures with adjacent atomic numbers.

Authors: De Backer, A; Zhang, Z; van den Bos, KHW; Bladt, E; Sánchez-Iglesias, A

• Publication status: Published
• Peer review status: Peer reviewed
• Publisher: Wiley
• Journal: small methods
• Volume: 6
• Issue: 11
• Article number: 2200875
• Publication date: 2022-09-30
• Acceptance date: 2022-08-29
• DOI: 10.1002/smtd.202200875
• EISSN: 2366-9608
• Pmid: 36180399
• Language: English
• Keywords: energy dispersive X-ray spectroscopy; FFR; statistical parameter estimation theory; scanning transmission electron microscopy; quantitative electron microscopy; atom-counting; bimetallic nanoparticles