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Dicyanovinyl-quinquethiophenes with varying alkyl chain lengths: Investigation of their performance in organic devices

Abstract:
We compare between two derivatives of dicyanovinyl-quinquethiophenes with different alkyl side chain lengths. Both materials show comparable open circuit voltages Voc in organic solar cells with fullerene C60 as acceptor, as expected since they have the same highest occupied molecular orbital energy. However, differences in the current-voltage-characteristics, particularly in the fill factor, are observed. We analyze both derivatives in hole-only devices and find a difference in the hole injection between the doped hole transport layer and the oligothiophenes. Additionally, we determine the hole mobility of the two materials and explain the different behaviors of the two materials in solar cells. © 2008 American Institute of Physics.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1063/1.2990071

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author


Publisher:
American Institute of Physics
Journal:
Journal of Applied Physics More from this journal
Volume:
104
Issue:
7
Article number:
074511
Publication date:
2008-01-01
DOI:
ISSN:
0021-8979


Language:
English
Pubs id:
pubs:405418
UUID:
uuid:4d08dc57-e358-4529-b32c-4bc1213a633c
Local pid:
pubs:405418
Source identifiers:
405418
Deposit date:
2013-09-26

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