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Correlating reactivity and selectivity to cyclopentadienyl ligand properties in Rh(III)-catalyzed C-H activation reactions: an experimental and computational study

Abstract:

Cp(X)Rh(III)-catalyzed C-H functionalization reactions are a proven method for the efficient assembly of small molecules. However, rationalization of the effects of cyclopentadienyl (Cp(X)) ligand structure on reaction rate and selectivity has been viewed as a black box, and a truly systematic study is lacking. Consequently, predicting the outcomes of these reactions is challenging because subtle variations in ligand structure can cause notable changes in reaction behavior. A predictive tool ...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1021/jacs.6b11670

Authors


Romanov-Michailidis, F More by this author
Romanova-Michaelides, M More by this author
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Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Semakul, N More by this author
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Publisher:
American Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
139
Issue:
3
Pages:
1296–1310
Publication date:
2017-01-06
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Pubs id:
pubs:670828
URN:
uri:4bbefbd3-e16c-4de7-b89e-ad04f3d1ecab
UUID:
uuid:4bbefbd3-e16c-4de7-b89e-ad04f3d1ecab
Local pid:
pubs:670828
Language:
English

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