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Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates

Abstract:

Using asymmetric catalysis to simultaneously form carbon-carbon bonds and generate single isomer products is strategically important. Suzuki-Miyaura cross-coupling is widely used in the academic and industrial sectors to synthesize drugs, agrochemicals and biologically active and advanced materials. However, widely applicable enantioselective Suzuki-Miyaura variations to provide 3D molecules remain elusive. Here we report a rhodium-catalyzed asymmetric Suzuki-Miyaura reaction with important p...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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10.1038/ncomms15762

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Department:
Oxford, MPLS, Chemistry, Organic Chemistry
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Author
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Department:
Oxford, MPLS, Chemistry, Organic Chemistry
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Author
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Department:
Oxford, MPLS, Chemistry, Organic Chemistry
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Author
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Department:
Keble College
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Author
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Funding agency for:
Schäfer, P
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Funding agency for:
Palacin, T
Publisher:
Springer Nature Publisher's website
Journal:
Nature Communications Journal website
Volume:
8
Pages:
Article: 15762
Publication date:
2017-06-13
Acceptance date:
2017-04-27
DOI:
ISSN:
2041-1723
Pubs id:
pubs:691330
URN:
uri:4b6c153b-994a-4412-a5ce-886d36622980
UUID:
uuid:4b6c153b-994a-4412-a5ce-886d36622980
Local pid:
pubs:691330

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