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Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates

Abstract:

Using asymmetric catalysis to simultaneously form carbon-carbon bonds and generate single isomer products is strategically important. Suzuki-Miyaura cross-coupling is widely used in the academic and industrial sectors to synthesize drugs, agrochemicals and biologically active and advanced materials. However, widely applicable enantioselective Suzuki-Miyaura variations to provide 3D molecules remain elusive. Here we report a rhodium-catalyzed asymmetric Suzuki-Miyaura reaction with important p...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1038/ncomms15762

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More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Oxford college:
Keble College
Role:
Author
More from this funder
Funding agency for:
Schäfer, P
Grant:
People Programme (Marie Curie Actions) FP7/2007-2013 316955
More from this funder
Funding agency for:
Palacin, T
Grant:
People Programme (Marie Curie Actions) FP7/2007-2013 316955
Publisher:
Springer Nature Publisher's website
Journal:
Nature Communications Journal website
Volume:
8
Article number:
15762
Publication date:
2017-06-13
Acceptance date:
2017-04-27
DOI:
ISSN:
2041-1723
Source identifiers:
691330
Pubs id:
pubs:691330
UUID:
uuid:4b6c153b-994a-4412-a5ce-886d36622980
Local pid:
pubs:691330
Deposit date:
2017-04-27

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