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Journal article

Fast electrochemical triple-interface processes at boron-doped diamond electrodes

Abstract:

Two important mechanisms for electron transfer processes at boron-doped diamond electrodes involving the oxidation of tetramethylphenylenediamine (TMPD) dissolved in aqueous solution and the oxidation of tetrahexylphenylenediamine (THPD) deposited in the form of microdroplets and immersed into aqueous eletrolyte solution are reported. For TMPD, the first oxidation step in aqueous solution follows the equation: TMPDaqueous ⇌ TMPDaqueous+ + e- Remarkably slow heterogeneous kinetics at a H-plasm...

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Publication status:
Published

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Publisher copy:
10.1007/s100080000122

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
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Journal:
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
Volume:
5
Issue:
2
Pages:
88-93
Publication date:
2001-02-01
DOI:
EISSN:
1433-0768
ISSN:
1432-8488
Source identifiers:
37700
Language:
English
Keywords:
UUID:
uuid:4afb939d-3a48-41db-9ff5-43e6ad899f83
Local pid:
pubs:37700
Deposit date:
2012-12-19

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