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On the Prins reaction of terminal olefins and formaldehyde in trifluoroacetic acid

Abstract:
The Prins reaction of 1-heptene, as a representative terminal alkene, with formaldehyde in trifluoroacetic acid produces 3-butyl-4-(trifluoroacetoxy)tetrahydropyran and/or 3-butyl-4-hydroxytetrahydropyran; it does not provide (as previously reported by Talipov and coworkers) a route to 3-alkyl-2,5-dihydrofurans and 4-alkyl-3-hydroxytetrahydrofurans.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1007/s10593-018-2293-z

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Organic Chemistry
Oxford college:
Oriel College
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Oxford college:
Oriel College
Role:
Author


Publisher:
Springer Verlag
Journal:
Chemistry of Heterocyclic Compounds More from this journal
Volume:
54
Issue:
4
Pages:
474–477
Publication date:
2018-06-07
Acceptance date:
2018-03-30
DOI:
EISSN:
1573-8353
ISSN:
0009-3122


Keywords:
Pubs id:
pubs:858813
UUID:
uuid:4a8ecdd9-80bf-410b-9370-d244e8c493da
Local pid:
pubs:858813
Source identifiers:
858813
Deposit date:
2018-09-24

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