- Abstract:
-
The low temperature (approximately 5 K) X-band ESR spectra are reported of the cyanide-bridged mixed-valence complexes [(OC)5Cr(mu-CN)M(NH3)5]X2 (M = Ru, Os; X = PF6(-)) in frozen matrices formed from nitromethane, acetonitrile and dimethylformamide with toluene. The anisotropy (g paralell-g perpendicular) is greater for the ruthenium than for the osmium complex. It is positive in all cases and is strongly dependent on the hydrogen-bonding interaction between the solvent matrix and the metal-...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/b810224d
-
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- Journal:
- Dalton transactions (Cambridge, England : 2003)
- Issue:
- 44
- Pages:
- 6257-6264
- Publication date:
- 2008-11-05
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- URN:
-
uuid:492df045-4d7a-459f-a32d-2b032bf6018e
- Source identifiers:
-
34469
- Local pid:
- pubs:34469
- Language:
- English
- Copyright date:
- 2008
Journal article
Solvent dependence of the g-anisotropy in the ESR of cyanide-bridged mixed-valence complexes.
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