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Solvent dependence of the g-anisotropy in the ESR of cyanide-bridged mixed-valence complexes.

Abstract:

The low temperature (approximately 5 K) X-band ESR spectra are reported of the cyanide-bridged mixed-valence complexes [(OC)5Cr(mu-CN)M(NH3)5]X2 (M = Ru, Os; X = PF6(-)) in frozen matrices formed from nitromethane, acetonitrile and dimethylformamide with toluene. The anisotropy (g paralell-g perpendicular) is greater for the ruthenium than for the osmium complex. It is positive in all cases and is strongly dependent on the hydrogen-bonding interaction between the solvent matrix and the metal-...

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Publication status:
Published

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Publisher copy:
10.1039/b810224d

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
44
Pages:
6257-6264
Publication date:
2008-11-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:492df045-4d7a-459f-a32d-2b032bf6018e
Source identifiers:
34469
Local pid:
pubs:34469
Language:
English

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