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Synthesis and structures of calcium and strontium 2,4-di-tert-butylphenolates and their reactivity towards the amine co-initiated ring-opening polymerisation of rac-lactide.

Abstract:

Calcium and strontium metals react with Hg(C6F5)2 and 2,4-di-tert-butylphenol (H-DBP) in tetrahydrofuran (THF) and 1,2-dimethoxyethane (DME) to give [Ca(DBP)2(THF)4] (1), [Ca2(DBP)4(DME)4(μ-DME)] (2), [Sr3(μ-DBP)6(THF)6] (3), and [Sr2(DBP)(μ-DBP)3(DME)3] (4). Compound 1 is a six coordinate trans-octahedral monomer, whereas in binuclear 2 two seven-coordinate Ca centres are bridged by a DME ligand. In 3 a central Sr is connected by three bridging DBP groups to each of two terminal Sr(THF)3 moi...

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Publication status:
Published

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Publisher copy:
10.1039/c3dt00065f

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
42
Issue:
25
Pages:
9294-9312
Publication date:
2013-07-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:48e683b3-f4a5-4087-a816-d386856b5f5c
Source identifiers:
387758
Local pid:
pubs:387758

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