Journal article
The first fully fluorinated organically templated materials: Synthesis, structures, and physical properties of [H3N(CH2)(3)NH3]U2F10 center dot 2H(2)O, [H3N(CH2)(4)NH3]U2F10 center dot 3H(2)O, [H3N(CH2)(6)NH3]U2F10 center dot 2H(2)O, and [HN(CH2CH2NH3)(3)]U5F24
- Abstract:
-
A series of new layered uranium(IV) fluorides have been prepared under hydrothermal conditions from UO2, HF, and H3PO4 by using H2N(CH2)nNH2 (n = 3, 4, or 6), and N(CH2-CH2NH2)3 as structure-directing agents. [H3N(CH2)3NH3]U2F 10·2H2O (UFO-1), [H3N(CH2)4-NH3]U2F 10·3H2O (UFO-2), [H3N(CH2)6NH3]U2F 10·2H2O (UFO-3), and [HN(CH2CH2NH3)3]-U5F 24 (UFO-4) have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, BET isotherms, and magnetic susceptibility measurements. ...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- CHEMISTRY OF MATERIALS
- Volume:
- 10
- Issue:
- 10
- Pages:
- 3131-3139
- Publication date:
- 1998-10-01
- DOI:
- ISSN:
-
0897-4756
- Source identifiers:
-
433457
Item Description
- Language:
- English
- Pubs id:
-
pubs:433457
- UUID:
-
uuid:4842ed53-4513-4bf2-a7d2-1621146f017f
- Local pid:
- pubs:433457
- Deposit date:
- 2013-11-17
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- Copyright date:
- 1998
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