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The first fully fluorinated organically templated materials: Synthesis, structures, and physical properties of [H3N(CH2)(3)NH3]U2F10 center dot 2H(2)O, [H3N(CH2)(4)NH3]U2F10 center dot 3H(2)O, [H3N(CH2)(6)NH3]U2F10 center dot 2H(2)O, and [HN(CH2CH2NH3)(3)]U5F24

Abstract:

A series of new layered uranium(IV) fluorides have been prepared under hydrothermal conditions from UO2, HF, and H3PO4 by using H2N(CH2)nNH2 (n = 3, 4, or 6), and N(CH2-CH2NH2)3 as structure-directing agents. [H3N(CH2)3NH3]U2F 10·2H2O (UFO-1), [H3N(CH2)4-NH3]U2F 10·3H2O (UFO-2), [H3N(CH2)6NH3]U2F 10·2H2O (UFO-3), and [HN(CH2CH2NH3)3]-U5F 24 (UFO-4) have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, BET isotherms, and magnetic susceptibility measurements. ...

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Publication status:
Published

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Publisher copy:
10.1021/cm980225x

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
CHEMISTRY OF MATERIALS
Volume:
10
Issue:
10
Pages:
3131-3139
Publication date:
1998-10-05
DOI:
ISSN:
0897-4756
URN:
uuid:4842ed53-4513-4bf2-a7d2-1621146f017f
Source identifiers:
433457
Local pid:
pubs:433457
Language:
English

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