Journal article

Gas sensing using edge-plane pyrolytic-graphite electrodes: electrochemical reduction of chlorine.

Abstract:: The voltammetric responses of chlorine in aqueous acid solutions have been explored using different carbon-based electrodes. Edge-plane pyrolytic graphite has more electrochemical reversibility than glassy carbon, basal-plane pyrolytic graphite, or boron-doped diamond electrodes. A significant reduction in the over-potential is observed on the edge-plane pyrolytic-graphite electrode in contrast with the other carbon-based electrode substrates. These results suggest that edge-plane pyrolytic graphite can be optimally used as the working electrodes in Clark-cell devices for low-potential amperometric gas sensing of Cl2.

Publication status:: Published

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APA Style

Lowe, E., Banks, C., & Compton, R. (2005). Gas sensing using edge-plane pyrolytic-graphite electrodes: electrochemical reduction of chlorine. Analytical and Bioanalytical Chemistry, 382(4), 1169–1174.

MLA Style

Lowe, E, et al. “Gas Sensing Using Edge-Plane Pyrolytic-Graphite Electrodes: Electrochemical Reduction of Chlorine.” Analytical and Bioanalytical Chemistry, vol. 382, no. 4, 2005, pp. 1169–74.

Chicago Style

Lowe, E, C Banks, and R Compton. 2005. “Gas Sensing Using Edge-Plane Pyrolytic-Graphite Electrodes: Electrochemical Reduction of Chlorine.” Analytical and Bioanalytical Chemistry 382 (4): 1169–74.
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Publisher copy:: 10.1007/s00216-005-3223-3

Authors

+ Lowe, E More by this author

Role:: Author

+ Banks, C More by this author

Role:: Author

+ Compton, R More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Physical & Theoretical Chem
Role:: Author

Journal:: Analytical and bioanalytical chemistry More from this journal
Volume:: 382
Issue:: 4
Pages:: 1169-1174
Publication date:: 2005-06-01
DOI:: 10.1007/s00216-005-3223-3
EISSN:: 1618-2650
ISSN:: 1618-2642

Language:: English
Keywords:: gas sensing

edge-plane pyrolytic graphite

chlorine

amperometric detection
UUID:: uuid:471ec6cc-9bff-426b-87cb-042037cc86bd
Local pid:: pubs:33092
Source identifiers:: 33092
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_471ec6cc9bff426b87cb042037cc86bd

Terms of use

Copyright date:: 2005

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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