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Comparative study of the magnetic properties of La3Ni2B'O9 for B' = Nb, Taor Sb

Abstract:

Polycrystalline samples of La 3 Ni 2 NbO 9 and La 3 Ni 2 TaO 9 have been characterised by X-ray and neutron diffraction, electron microscopy, magnetometry and muon spin relaxation (µSR); the latter technique was also applied to La 3 Ni 2 SbO 9 . On the length scale of a neutron diffraction experiment, the six-coordinate sites of the monoclinic perovskite structure are occupied in a 1:1 ordered manner by Ni and a random ⅓Ni/⅔B′ mixture. Electron microscopy demonstrated that this 1:1 ordering i...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1016/j.jssc.2017.12.018

Authors


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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
St Catherines College
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Physics; Condensed Matter Physics
Oxford college:
Mansfield College
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Physics; Condensed Matter Physics
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Publisher:
Elsevier Publisher's website
Journal:
Journal of Solid State Chemistry Journal website
Volume:
258
Pages:
825-834
Publication date:
2017-12-20
Acceptance date:
2017-12-15
DOI:
ISSN:
0022-4596
Pubs id:
pubs:813809
URN:
uri:45b27e46-0958-4302-a997-0e5dcaba065f
UUID:
uuid:45b27e46-0958-4302-a997-0e5dcaba065f
Local pid:
pubs:813809

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