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On the mercuration, palladation, transmetalation and direct auration of a C^N^C pincer ligand

Abstract:
The C^N^C ligand 2,6-bis(2,3-dialkoxyphenyl)pyridine forms dimercury and orthopalladated complexes, both of which may be transmetallated to gold(iii) complexes; the gold complexes may also be formed directly in a Rh(iii)-catalysed process, hence it is possible to circumvent the use of organomercury intermediates in the synthesis of this important class of compound
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/d2dt04114f

Authors

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Role:
Author
ORCID:
0000-0003-0459-5470
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Institution:
University of Oxford
Role:
Author
ORCID:
0000-0002-5834-8371
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Role:
Author
ORCID:
0000-0002-5132-5468
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Role:
Author
ORCID:
0000-0003-0103-9479
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Role:
Author
ORCID:
0000-0002-1365-2222


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Funder identifier:
https://ror.org/04m01e293


Publisher:
Royal Society of Chemistry
Journal:
Dalton Transactions More from this journal
Volume:
52
Issue:
4
Pages:
872-876
Publication date:
2023-01-24
DOI:
EISSN:
1477-9234
ISSN:
1477-9226


Language:
English
Keywords:
Pubs id:
2343933
Local pid:
pubs:2343933
Source identifiers:
W4313494583
Deposit date:
2025-12-04
ARK identifier:
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