- Abstract:
-
Voltammetry is reported for chlorine, Cl2, dissolved in various room temperature ionic liquids using platinum microdisk electrodes. A single reductive voltammetric wave is seen and attributed to the two-electron reduction of chlorine to chloride. Studies of the effect of voltage scan rate reveal uniquely unusual behavior in which the magnitude of the currents decrease with increasing scan rates. A model for this is proposed and shown to indicate the presence of strongly adsorbed species in th...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/jp8082437
-
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- Journal:
- JOURNAL OF PHYSICAL CHEMISTRY C
- Volume:
- 112
- Issue:
- 49
- Pages:
- 19477-19483
- Publication date:
- 2008-12-11
- DOI:
- EISSN:
-
1932-7455
- ISSN:
-
1932-7447
- URN:
-
uuid:456ececc-c247-4b1c-b18c-0b1d12f8e572
- Source identifiers:
-
41033
- Local pid:
- pubs:41033
- Language:
- English
- Copyright date:
- 2008
Journal article
Electroreduction of Chlorine Gas at Platinum Electrodes in Several Room Temperature Ionic Liquids: Evidence of Strong Adsorption on the Electrode Surface Revealed by Unusual Voltammetry in Which Currents Decrease with Increasing Voltage Scan Rates
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