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Luminescence and upconversion from thulium(III) species in solution.

Abstract:

Thulium salts and complexes are shown to be emissive from three states in the excited state manifold of Tm(3+). Formation of the (1)D(2) state can result in luminescence, or in energy transfer to the lower energy (1)G(4) and (3)H(4) emissive states. Where chromophores are present in the ligand structure, emission is restricted to thulium centred emissive states that are lower in energy than the chromophore centred donor state. We have also observed direct multi-photon excitation of the thuliu...

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Publication status:
Published

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Publisher copy:
10.1039/c2cp42228j

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
14
Issue:
38
Pages:
13378-13384
Publication date:
2012-10-01
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Source identifiers:
350490
Language:
English
Pubs id:
pubs:350490
UUID:
uuid:454a3471-7f44-45de-8f0d-d1829d4a075c
Local pid:
pubs:350490
Deposit date:
2012-12-19

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