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Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones

Abstract:
Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k0 on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and the predictions are compared to experimental measurements.
Publication status:
Published

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Publisher copy:
10.1021/jp040382l

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Journal:
JOURNAL OF PHYSICAL CHEMISTRY B More from this journal
Volume:
108
Issue:
34
Pages:
13047-13051
Publication date:
2004-08-26
DOI:
EISSN:
1520-5207
ISSN:
1520-6106


Language:
English
UUID:
uuid:43f207ca-06f4-4937-963e-6bda7b51b72c
Local pid:
pubs:39118
Source identifiers:
39118
Deposit date:
2012-12-19
ARK identifier:

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