Journal article
Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones
- Abstract:
- Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k0 on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and the predictions are compared to experimental measurements.
- Publication status:
- Published
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- Publisher copy:
- 10.1021/jp040382l
Authors
- Journal:
- JOURNAL OF PHYSICAL CHEMISTRY B More from this journal
- Volume:
- 108
- Issue:
- 34
- Pages:
- 13047-13051
- Publication date:
- 2004-08-26
- DOI:
- EISSN:
-
1520-5207
- ISSN:
-
1520-6106
- Language:
-
English
- UUID:
-
uuid:43f207ca-06f4-4937-963e-6bda7b51b72c
- Local pid:
-
pubs:39118
- Source identifiers:
-
39118
- Deposit date:
-
2012-12-19
- ARK identifier:
Terms of use
- Copyright date:
- 2004
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