Journal article

Fluorine-directed diastereoselective iodocyclizations.

Abstract:: (Chemical Equation Presented) An inside job: β-Fluorinated lactones and tetrahydrofurans are synthesized by iodocyclization of various allylic fluorides. The fluorine substituent acts as a highly efficient syn-stereodirecting group for the ring closure. The experimental results combined with theoretical studies provide evidence in support of an "inside fluoro effect" to account for the sense and level of stereocontrol of these reactions. © 2008 Wiley-VCH Verlag GmbH and Co. KGaA.

Publication status:: Published

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APA Style

Tredwell, M., Luft, J., Schuler, M., Tenza, K., Houk, K., & Gouverneur, V. (2008). Fluorine-directed diastereoselective iodocyclizations. Angewandte Chemie (International Ed. in English), 47(2), 357–360.

MLA Style

Tredwell, M., et al. “Fluorine-Directed Diastereoselective Iodocyclizations.” Angewandte Chemie (International Ed. in English), vol. 47, no. 2, 2008, pp. 357–60.

Chicago Style

Tredwell, M, J Luft, M Schuler, K Tenza, K Houk, and V Gouverneur. 2008. “Fluorine-Directed Diastereoselective Iodocyclizations.” Angewandte Chemie (International Ed. in English) 47 (2): 357–60.
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Publisher copy:: 10.1002/anie.200703465

Authors

+ Tredwell, M More by this author

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+ Luft, J More by this author

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+ Schuler, M More by this author

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+ Tenza, K More by this author

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+ Houk, K More by this author

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Journal:: Angewandte Chemie (International ed. in English) More from this journal
Volume:: 47
Issue:: 2
Pages:: 357-360
Publication date:: 2008-01-01
DOI:: 10.1002/anie.200703465
EISSN:: 1521-3773
ISSN:: 1433-7851

Language:: English
Keywords:: Fluorine

Stereoisomerism

Ions

Models, Molecular

Molecular Structure

Iodine

Bromine

Cyclization
Pubs id:: pubs:34051
UUID:: uuid:432e56a3-5956-4340-80f9-49b39f4cf75c
Local pid:: pubs:34051
Source identifiers:: 34051
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2008

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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