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The information-theoretic foundation of thermodynamic work extraction

Abstract:
Abstract In this paper I demonstrate a novel distinction between work and heat, in terms of the distinguishability of states. Specifically, I show that if it is possible to extract different amounts of work deterministically from a physical system prepared in any one of a set of states, then those states must be distinguishable from one another. This result is formulated independently of scale and of particular dynamical laws; it also provides a novel connection between thermodynamics and information theory, established via the law of conservation of energy. This connection, unlike the well-known one between information and the second law, is exact, i.e., it does not depend on coarse-graining or ensemble approximation. Albeit compatible with these conclusions, existing thermodynamics approaches cannot provide a result of such generality, because they are scale-dependent (relying on ensembles or coarse-graining) or tied to particular dynamical laws. This result provides a foundation for thermodynamics that is both broader and more secure than existing ones, with implications for the theory of von Neumann’s universal constructor.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1088/2399-6528/ac70a7

Authors

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Institution:
University of Oxford
Role:
Author
ORCID:
0000-0002-2690-4433


Publisher:
IOP Publishing
Journal:
Journal of Physics Communications More from this journal
Volume:
6
Issue:
5
Pages:
055012-055012
Publication date:
2022-05-27
DOI:
EISSN:
2399-6528
ISSN:
2399-6528


Language:
English
Keywords:
Pubs id:
1264011
Local pid:
pubs:1264011
Source identifiers:
W3174260196
Deposit date:
2026-04-24
ARK identifier:
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