- Abstract:
-
The finite difference method is used to perform 2D numerical simulation of chronoamperometry and voltammetry at a hypothesised "annular microband" (AMB) electrode. The diffusional properties of this electrode system are inferred from the results of simulations and are found to be highly efficient. Comparison is drawn with infinite limiting cases of the geometry, which are shown not to support mass-transport limited steady-state diffusion, whereas the AMB supports such a steady state. Lastly, ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/j.jelechem.2008.10.002
-
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- Journal:
- JOURNAL OF ELECTROANALYTICAL CHEMISTRY
- Volume:
- 625
- Issue:
- 1
- Pages:
- 40-46
- Publication date:
- 2009
- DOI:
- ISSN:
-
1572-6657
- URN:
-
uuid:40486d5a-4bc1-4fe1-a232-0f46d1b04329
- Source identifiers:
-
41073
- Local pid:
- pubs:41073
- Copyright date:
- 2009
Journal article
Theory of diffusion to an "annular microband" electrode
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