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Gold-palladium core-shell nanocrystals with size and shape control optimized for catalytic performance

Abstract:
Right to the core: The design of nanocatalysts with maximized catalytic performance relies on control of the size, shape, and composition. The shell thickness of nanocrystals with core-shell structures can be controlled, thus enabling control over the nanocrystal electronic structure and catalytic properties. Monodisperse faceted icosahedral Au-Pd core-shell nanocrystals (see picture) were synthesized, and optimized for the oxidation of benzyl alcohol to benzaldehyde. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.

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Publisher copy:
10.1002/anie.201207824

Authors


Henning, AM More by this author
Miedziak, PJ More by this author
Santonastaso, M More by this author
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Journal:
Angewandte Chemie - International Edition
Volume:
52
Issue:
5
Pages:
1477-1480
Publication date:
2013-01-28
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:3f7a2222-b8ba-40df-ad0c-0224c80c6b9a
Source identifiers:
382921
Local pid:
pubs:382921

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