Journal article
Discrimination of chiral guests by chiral channels: variable temperature studies by SXRD and solid state 13C NMR of the deoxycholic acid complexes of camphorquinone and endo-3-bromocamphor.
- Abstract:
-
3alpha,12alpha-dihydroxy-5beta-cholan-24-oic acid (deoxycholic acid DCA) is able to discriminate between the R- and S-enantiomers of camphorquinone and endo-(+)-3-bromocamphor and select only the S-enantiomers from a racemic mixture. DCA forms novel well ordered 1:1 adducts with (1S)-(+)-camphorquinone and (1S)-endo-(-)-3-bromocamphor, both of which have been characterized by single crystal X-ray diffraction (SXRD). When DCA is cocrystallized with (RS)-camphorquinone and (RS)-endo-3-bromocamp...
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- Publication status:
- Published
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- Publisher copy:
- 10.1002/chir.20561
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Bibliographic Details
- Journal:
- Chirality
- Volume:
- 20
- Issue:
- 7
- Pages:
- 863-870
- Publication date:
- 2008-07-01
- DOI:
- EISSN:
-
1520-636X
- ISSN:
-
0899-0042
- Source identifiers:
-
104430
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:104430
- UUID:
-
uuid:3ebbff67-9fb1-48f0-ab7f-82cb772e9392
- Local pid:
- pubs:104430
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2008
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