Journal article

Filling vacancies in a Prussian blue analogue using mechanochemical post-synthetic modification

Abstract:: Mechanochemical grinding of polycrystalline powders of the Prussian blue analogue (PBA) Mn[Co(CN)6]2/3□1/3·xH2O and K3Co(CN)6 consumes the latter and chemically modifies the former. A combination of inductively-coupled plasma and X-ray powder diffraction measurements suggests the hexacyanometallate vacancy fraction in this modified PBA is reduced by approximately one third under the specific conditions we explore. We infer the mechanochemically-driven incorporation of [Co(CN)6]3− ions onto the initially-vacant sites, coupled with intercalation of charge-balancing K+ ions within the PBA framework cavities. Our results offer a new methodology for the synthesis of low-vacancy PBAs.

Publication status:: Published

Peer review status:: Peer reviewed

Actions

Email

Email this record

Send the bibliographic details of this record to your email address.

Your Email
Please enter the email address that the record information will be sent to.

-
Your message (optional)
Please add any additional information to be included within the email.
Cite

Cite this record

APA Style

Cattermull, J., Wheeler, S., Hurlbutt, K., Pasta, M., & Goodwin, A. L. (2020). Filling vacancies in a Prussian blue analogue using mechanochemical post-synthetic modification. Chemical Communications, 56(57), 7873–7876.

MLA Style

Cattermull, J., et al. “Filling Vacancies in a Prussian Blue Analogue Using Mechanochemical Post-Synthetic Modification.” Chemical Communications, vol. 56, no. 57, Royal Society of Chemistry, 2020, pp. 7873–76.

Chicago Style

Cattermull, J, S Wheeler, K Hurlbutt, M Pasta, and AL Goodwin. 2020. “Filling Vacancies in a Prussian Blue Analogue Using Mechanochemical Post-Synthetic Modification.” Chemical Communications 56 (57): 7873–76.
Share
Print

Access Document

Files:: Cattermull et al Rilling vacancies in a Prussian blue analogue...

(Preview, Version of record, 2.6MB, Terms of use)

Publisher copy:: 10.1039/d0cc02922j

Authors

+ Cattermull, J More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Wheeler, S More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Materials
Role:: Author

+ Hurlbutt, K More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Materials
Role:: Author

+ Pasta, M More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Materials
Role:: Author
ORCID:: 0000-0002-2613-4555

+ Goodwin, AL More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Oxford college:: St Anne's College
Role:: Author
ORCID:: 0000-0001-9231-3749

Publisher:: Royal Society of Chemistry
Journal:: Chemical Communications More from this journal
Volume:: 56
Issue:: 57
Pages:: 7873-7876
Publication date:: 2020-06-04
Acceptance date:: 2020-06-04
DOI:: 10.1039/d0cc02922j
EISSN:: 1364-548X
ISSN:: 1359-7345
Pmid:: 32529992

Language:: English
Keywords:: FFR
Pubs id:: 1113142
Local pid:: pubs:1113142
Deposit date:: 2020-09-29

Terms of use

Copyright holder:: Royal Society of Chemistry
Copyright date:: 2020
Rights statement:: © The Royal Society of Chemistry 2020. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Licence:: CC Attribution-NonCommercial (CC BY-NC)

Views and Downloads

About views and downloads

If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP