Journal article

Stereoselective methodology for 1-aryl-1-alkyl epoxides via chromium tricarbonyl complexes

Abstract:: Treatment of (1RS, SSR)-(1-phenylsulfinyl-2-valeryl benzene) chromium tricarbonyl 2 with a sulfur ylide results in a highly diastereoselective epoxide formation (d.s.>96:4). Regioselective opening of the epoxide, employing an in situ trapping protocol, allows the synthesis of a highly functionalised, diastereomerically pure benzylic alcohol.

Publication status:: Published

Actions

Email

Email this record

Send the bibliographic details of this record to your email address.

Your Email
Please enter the email address that the record information will be sent to.

-
Your message (optional)
Please add any additional information to be included within the email.
Cite

Cite this record

APA Style

Davies, S., Loveridge, T., & Clough, J. (1997). Stereoselective methodology for 1-aryl-1-alkyl epoxides via chromium tricarbonyl complexes. SYNLETT, 1997(1), 66-and.

MLA Style

Davies, S., et al. “Stereoselective Methodology for 1-Aryl-1-Alkyl Epoxides via Chromium Tricarbonyl Complexes.” SYNLETT, vol. 1997, no. 1, 1997, pp. 66-and.

Chicago Style

Davies, S, T Loveridge, and J Clough. 1997. “Stereoselective Methodology for 1-Aryl-1-Alkyl Epoxides via Chromium Tricarbonyl Complexes.” SYNLETT 1997 (1): 66-and.
Share
Print

Access Document

Publisher copy:: 10.1055/s-1997-705

Authors

+ Davies, S More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

+ Loveridge, T More by this author

Role:: Author

+ Clough, J More by this author

Role:: Author

Journal:: SYNLETT More from this journal
Volume:: 1997
Issue:: 1
Pages:: 66-and
Publication date:: 1997-01-01
DOI:: 10.1055/s-1997-705
EISSN:: 1437-2096
ISSN:: 0936-5214

Keywords:: stereoselective

chromium tricarbonyl

epoxide formation
Pubs id:: pubs:110835
UUID:: uuid:3c38c3eb-c4f3-4244-97a1-79c2ac61b825
Local pid:: pubs:110835
Source identifiers:: 110835
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 1997

Licence:: Terms and Conditions of Use for Oxford University Research Archive

Views and Downloads

About views and downloads

If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP