Journal article

Stereoselective methodology for 1-aryl-1-alkyl epoxides via chromium tricarbonyl complexes

Abstract:: Treatment of (1RS, SSR)-(1-phenylsulfinyl-2-valeryl benzene) chromium tricarbonyl 2 with a sulfur ylide results in a highly diastereoselective epoxide formation (d.s.>96:4). Regioselective opening of the epoxide, employing an in situ trapping protocol, allows the synthesis of a highly functionalised, diastereomerically pure benzylic alcohol.

Publication status:: Published

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APA Style

Davies, S., Loveridge, T., & Clough, J. (1997). Stereoselective methodology for 1-aryl-1-alkyl epoxides via chromium tricarbonyl complexes. SYNLETT, 1997(1), 66-and.

MLA Style

Davies, S., et al. “Stereoselective Methodology for 1-Aryl-1-Alkyl Epoxides via Chromium Tricarbonyl Complexes.” SYNLETT, vol. 1997, no. 1, 1997, p. 66-and.

Chicago Style

Davies, S., T. Loveridge, and J. Clough. 1997. “Stereoselective Methodology for 1-Aryl-1-Alkyl Epoxides via Chromium Tricarbonyl Complexes.” SYNLETT 1997 (1): 66-and.
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Publisher copy:: 10.1055/s-1997-705

Authors

+ Davies, S More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

+ Loveridge, T More by this author

Role:: Author

+ Clough, J More by this author

Role:: Author

Journal:: SYNLETT More from this journal
Volume:: 1997
Issue:: 1
Pages:: 66-and
Publication date:: 1997-01-01
DOI:: 10.1055/s-1997-705
EISSN:: 1437-2096
ISSN:: 0936-5214

Keywords:: stereoselective

epoxide formation

chromium tricarbonyl
Pubs id:: pubs:110835
UUID:: uuid:3c38c3eb-c4f3-4244-97a1-79c2ac61b825
Local pid:: pubs:110835
Source identifiers:: 110835
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_3c38c3ebc4f3424497a179c2ac61b825

Terms of use

Copyright date:: 1997

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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