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Inositol adenophostin: convergent synthesis of a potent agonist of D-myo-inositol 1,4,5-trisphosphate receptors

Abstract:

D-myo-Inositol 1,4,5-trisphosphate receptors (IP3Rs) are Ca2+ channels activated by the intracellular messenger inositol 1,4,5-trisphosphate (IP3, 1). The glyconucleotide adenophostin A (AdA, 2) is a potent agonist of IP3Rs. A recent synthesis of D-chiro-inositol adenophostin (InsAdA, 5) employed suitably- protected chiral building blocks and replaced the d-glucose core by d-chiro-inositol. An alternative approach to fully chiral material is now reported using intrinsic sugar chirality to av...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acsomega.0c04145

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Institution:
University of Oxford
Division:
MSD
Department:
Pharmacology
Role:
Author
ORCID:
0000-0003-3255-9135
Publisher:
American Chemical Society
Journal:
ACS Omega More from this journal
Volume:
5
Issue:
44
Pages:
28793–28811
Publication date:
2020-10-28
Acceptance date:
2020-10-08
DOI:
EISSN:
2470-1343
Language:
English
Keywords:
Pubs id:
1136453
Local pid:
pubs:1136453
Deposit date:
2020-10-08

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